Blach shale deposition is important to petroleum source rocks and marks significant climate-ocean changes in Earth’s history. This week, we will look at two Cretaceous black shales. Also, this edition of Core Elements introduces a new segment, “The Lighthearted Layer,” for fun reading. Enjoy it!
Rasoul Sorkhabi
Editor, Core Elements
Caribbean Link to 88-Ma Global Oceanic Anoxic Event
Landscape of the Nicoya Peninsula/Wikimedia Commons
A paper in Global Planetary Change traces the cause of a global oceanic anoxic event (OAE) of Coniacian-Santonian age (90–84 Ma) to the peak Caribbean Large Igneous Province (ILP) volcanism at 88 Ma.
Cretaceous OAEs:
OAEs are important markers of global climate warming, planktonic proliferation, ocean water acidification, and organic-rich shale deposition.
Three OAEs have been recorded during the Cretaceous:
OAE1 (120–100 Ma)
OAE2 (94 Ma)
OAE3 (88–84 Ma)
What they did:
Goran Andjić and colleagues studied the Chumico Formation at three localities on the Nicoya Peninsula of Costa Rica’s Pacific coast.
They applied zircon U-Pb dating and radiolarian biostratigraphy to tuffs and volcaniclastic sediments interbedded with the black shales of the Loma Chumico Formation.
They also determined the concentrations of mercury and total organic carbon, as well as the ratios of stable carbon isotopes on coeval carbonate samples from Hole 700B and Hole U1513A.
These holes were drilled on the northeastern slope of the Northeast Georgia Rise in the South Atlantic.
About the Loma Chumico Formation:
This formation overlies a mafic basement of 94–89 Ma, composed of basalt and intruded by dolerite and gabbro rocks. The mafic basement exhibits a typical plume-derived LIP.
It is a deepwater, volcaniclastic, and black shale formation deposited in the Tempisque Forearc Basin in northern Costa Rica.
What they found: Geochronologic coincidence and geochemical signature (such as high mercury abundance) of the samples indicate that Caribbean LIP volcanism between 88 and 86 Ma probably triggered the organic-rich OAE3 event.
Why it matters:
Cretaceous OAE3 is the latest of its kind in Earth’s history.
While OAE3 has been recorded in marine and terrestrial sediments, its relationship with a coeval black shale deposition and LIP was not empirically established.
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The Geochemistry of Pre-Salt Petroleum Source Rocks Offshore Brazil
Pre-salt oil and gas fields of Brazil/Agência Nacional Do Petróleo
A group of scientists from Brazil has published a paper inMarine Geoscience and Energy Resources that details organic matter preservation in Lower Cretaceous pre-salt shale formation in the Santos and Campos basins offshore Brazil.
What they did:
The researchers collected samples of Jiquia Shale and analyzed 50 samples from four wells.
They employed XRC, XRD, and RockEval methods to obtain geochemical and mineralogical data.
Jiquia Shale: This lacustrine sedimentary rock was deposited during the Jiquia Stage (biozones NRT-008/009 to NRT-010) in the Middle Aptian under predominantly anoxic bottom-water conditions.
What they found:
The study indicated contrasting depositional architectures across the Santos and Campos basins.
In the Santos Basin, the Jiquia stage sediments were developed in a predominantly carbonate-dominated system (74.6 ± 10.7 percent total carbonates) with consistently higher TOC values (5.1 ± 1.1 percent).
In the Campos Basin, the sediments were developed in a mixed carbonate-siliciclastic system (38.3 ± 13.0 percent carbonates) with more variable and lower TOC contents (3.1 ± 1.3 percent).
The Jiquia stage shale concentrated in the Coqueiros Formation (Campos Basin) and Itapema Formation (Santos Basin) is a major pre-salt source rock.
Why it matters:
Pre-salt reservoirs in the Santos and Campos basins are among the most prolific oil and gas accumulations in Brazil.
This paper contributes to our knowledge of pre-salt source rocks charging these reservoirs.
Introducing: The Lighthearted Layer
Book cover courtesy of Amazon
The Lighthearted Layer is a new segment in Core Elements meant to take a step back from technical geoscience to share a piece of wit and/or wisdom. I hope you enjoy it and find it interesting! If you want to contribute a piece of geoscience-related wit or wisdom for this section, email editorial@aapg.org
Now, for today’s segment…
When Richard Selley published his classic text Ancient Sedimentary Environments in 1970, he included this confession in the acknowledgments:
“I am extremely grateful to Professor J. Sutton and the Imperial College authorities who granted me leave of absence to retire from the academic hurly-burly to the peace and quiet of the oil industry to write this book.”
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