Partial melting of a subducting oceanic plate is considered a main source and formation process for copper-silver-gold-molybdenum deposits in magmatic arcs worldwide. However, exact processes and genetic relationships constrained by empirical data remain poorly understood.
Two studies published in the February issue of Geology offer interesting insights into these problems.
Study #1: Magmatic Anhydrites in the Laramide Magmatic Arc in the Southwestern United States
Magmatic anhydrite background:
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Anhydrite is a rare mineral phase in magmatic rocks because it does not survive and decomposes in the near-surface groundwater zone.
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In 1984, Luhr et al. first discovered magmatic anhydrite in volcanic ejecta from the El Chichón Volcano in Mexico.
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Since then, 33 other cases have been documented in intrusive and extrusive rocks from the Philippines, Indonesia, and the United States.
The new study:
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Andreas Audétat and colleagues report on the presence of magmatic anhydrite inclusions in rock samples collected from igneous stocks and dikes associated with porphyry copper-gold-molybdenum deposits in Arizona and New Mexico.
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The samples come from magma systems of the Laramide orogenic event, dating from 40 to 80 Ma.
Why it matters: Anhydrite saturation in subduction melts indicates oxidizing conditions and high magmatic sulfur contents, which are necessary for the genesis of porphyry chalcophile deposits.
Study #2: Slab Melting and Sulfide Solutions Beneath the Western Aleutian Arc
The Aleutian island arc is a unique tectonic setting because it represents the active subduction of two oceanic plates: the Pacific (and preceding Kula) plate to the south and the oceanic segment of the North American plate. The region thus offers nearly unmodified primitive melt samples.
The new study: Maxim Portnyagin and colleagues report on a study of chalcophile and siderophile elements from rock samples collected from the Western Aleutian Islands.
What they did: The researchers collected subduction-related magnesium-rich rhyodacites, andesite, as well as eclogitized mid-ocean ridge basalts, and analyzed them for trace elements using LA-ICP mass spectrometry and optical petrography.
What they found:
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The study found the presence of anhydrite phenocrysts and hornblende composition, which indicate highly oxidizing conditions of crystallization.
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The rocks exhibit strongly fractionated chalcophile element ratios, such as high Ag/Cu and Bi/Cu ratios.
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No sulfides were present in the mineral assemblage, although sulfide oxidation is critical for porphyry copper deposits.
What it means:
Why it matters: When sulfide minerals oxidize, they trigger a series of chemical reactions that influence the speciation and mobility of metals, including copper.
Go deeper: See this paper in Communications Earth & Environment on sulfide oxidation control on and porphyry copper deposits to learn even more.